atomic structure

atoms were particles of elements, substances that could not be broken down further. In examining atomic structure though, we have to clarify this statement. An atom cannot be broken down further without changing the chemical nature of the substance. For example, if you have 1 ton, 1 gram or 1 atom of oxygen, all of these units have the same properties. We can break down the atom of oxygen into smaller particles, however, when we do the atom looses its chemical properties. For example, if you have 100 watches, or one watch, they all behave like watches and tell time. You can dismantle one of the watches: take the back off, take the batteries out, peer inside and pull things out. However, now the watch no longer behaves like a watch. So what does an atom look like inside?
Atoms are made up of 3 types of particles electrons , protons and neutrons . These particles have different properties. Electrons are tiny, very light particles that have a negative electrical charge (-). Protons are much larger and heavier than electrons and have the opposite charge, protons have a positive charge. Neutrons are large and heavy like protons, however neutrons have no electrical charge. Each atom is made up of a combination of these particles. Let's look at one type of atom:

A neutron walked into a bar and
asked how much for a drink.
The bartender replied,
"for you, no charge."
-Jaime - Internet Chemistry Jokes

The atom above, made up of one proton and one electron, is called hydrogen (the abbreviation for hydrogen is H). The proton and electron stay together because just like two magnets, the opposite electrical charges attract each other. What keeps the two from crashing into each other? The particles in an atom are not still. The electron is constantly spinning around the center of the atom (called the nucleus). The centrigugal force of the spinning electron keeps the two particles from coming into contact with each other much as the earth's rotation keeps it from plunging into the sun. Taking this into consideration, an atom of hydrogen would look like this:
A Hydrogen Atom

Keep in mind that atoms are extremely small. One hydrogen atom, for example, is approximately 5 x 10-8 mm in diameter. To put that in perspective, this dash - is approximately 1 mm in length, therefore it would take almost 20 million hydrogen atoms to make a line as long as the dash. In the sub-atomic world, things often behave a bit strangely. First of all, the electron actually spins very far from the nucleus. If we were to draw the hydrogen atom above to scale, so that the proton were the size depicted above, the electron would actually be spinning approximately 0.5 km (or about a quarter of a mile) away from the nucleus. In other words, if the proton was the size depicted above, the whole atom would be about the size of Giants Stadium. Another peculiarity of this tiny world is the particles themselves. Protons and neutrons behave like small particles, sort of like tiny billiard balls. The electron however, has some of the properties of a wave. In other words, the electron is more similar to a beam of light than it is to a billiard ball. Thus to represent it as a small particle spinning around a nucleus is slightly misleading. In actuality, the electron is a wave that surrounds the nucleus of an atom like a cloud. While this is difficult to imagine, the figure below may help you picture what this might look like:

Hydrogen: a proton surrounded by an electron cloud


While you should keep in mind that electrons actually form clouds around their nucleii, we will continue to represent the electron as a spinning particle to keep things simple.
In an electrically neutral atom, the positively charged protons are always balanced by an equal number of negatively charged electrons. As we have seen, hydrogen is the simplest atom with only one proton and one electron. Helium is the 2nd simplest atom. It has two protons in its nucleus and two electrons spinning around the nucleus. With helium though, we have to introduce another particle. Because the 2 protons in the nucleus have the same charge on them, they would tend to repel each other, and the nucleus would fall apart. To keep the nucleus from pushing apart, helium has two neutrons in its nucleus. Neutrons have no electrical charge on them and act as a sort of nuclear glue, holding the protons, and thus the nucleus, together.

A Helium Atom

As you can see, helium is larger than hydrogen. As you add electrons, protons and neutrons, the size of the atom increases. We can measure an atom's size in two ways: using the atomic number (Z) or using the atomic mass (A, also known as the mass number). The atomic number describes the number of protons in an atom. For hydrogen the atomic number, Z, is equal to 1. For helium Z = 2. Since the number of protons equals the number of electrons in the neutral atom, Z also tells you the number of electrons in the atom. The atomic mass tells you the number of protons plus neutrons in an atom. Therefore, the atomic mass, A, of hydrogen is 1. For helium A = 4.

Ions and Isotopes
So far we have only talked about electrically neutral atoms, atoms with no positive or negative charge on them. Atoms, however, can have electrical charges. Some atoms can either gain or lose electrons (the number of protons never changes in an atom). If an atom gains electrons, the atom becomes negatively charged. If the atom loses electrons, the atom becomes positively charged (because the number of positively charged protons will exceed the number of electrons). An atom that carries an electrical charge is called an ion. Listed below are three forms of hydrogen; 2 ions and the electrically neutral form.

H+ : a positively charged hydrogen ion H : the hydrogen atom H- : a negatively charged hydrogen ion


Neither the number of protons nor neutrons changes in any of these ions, therefore both the atomic number and the atomic mass remain the same. While the number of protons for a given atom never changes, the number of neutrons can change. Two atoms with different numbers of neutrons are called isotopes. For example, an isotope of hydrogen exists in which the atom contains 1 neutron (commonly called deuterium). Since the atomic mass is the number of protons plus neutrons, two isotopes of an element will have different atomic masses (however the atomic number, Z, will remain the same).

Two isotopes of hydrogen

Hydrogen
Atomic Mass = 1
Atomic Number = 1 Deuterium
Atomic Mass = 2
Atomic Number = 1


If you would like to explore the interaction of protons and electrons further, the University of Colorado's Physics 2000 site has an interesting experiment posted on line. At the Electrical Force page, you can place an electron next to a proton and see how the electron moves. You can even try to build your own atom (and see how difficult it is)!

An atom is the smallest building block of matter. Atoms are made of neutrons, protons and electrons. The nucleus of an atom is extremely small in comparison to the atom. If an atom was the size of the Houston Astrodome, then its nucleus would be the size of a pea.

* Introduction to the Periodic Table
* Charges in the Atom
* Atomic Models and the Quantum Numbers
* Determining Electron Configuration

Introduction to the Periodic Table
Scientists use the Periodic Table in order to find out important information about various elements. Created by Dmitri Mendeleev (1834-1907), the periodic table orders all known elements in accordance to their similarities. When Mendeleev began grouping elements, he noticed the Law of Chemical Periodicity. This law states, "the properties of the elements are periodic functions of atomic number." The periodic table is a chart that categorizes elements by "groups" and "periods." All elements are ordered by their atomic number. The atomic number is the number of protons per atom. In a neutral atom, the number of electrons equals the number of protons. The periodic table represents neutral atoms. The atomic number is typically located above the element symbol. Beneath the element symbol is the atomic mass. Atomic mass is measured in Atomic Mass Units where 1 amu = (1/12) mass of carbon measured in grams. The atomic mass number is equal to the number of protons plus neutrons, which provides the average weight of all isotopes of any given element. This number is typically found beneath the element symbol. Atoms with the same atomic number, but different mass numbers are called isotopes. Below is a diagram of a typical cells on the periodic table.

There are two main classifications in the periodic table, "groups" and "periods." Groups are the vertical columns that include elements with similar chemical and physical properties. Periods are the horizontal rows. Going from left to right on the periodic table, you will find metals, then metalloids, and finally nonmetals. The 4th, 5th, and 6th periods are called the transition metals. These elements are all metals and can be found pure in nature. They are known for their beauty and durability. The transition metals include two periods known as the lanthanides and the actinides, which are located at the very bottom of the periodic table. The chart below gives a brief description of each group in the periodic table.
Group 1A

* Known as Alkali Metals
* Very reactive
* Never found free in nature
* React readily with water

Group 2A

* Known as Alkaline earth elements
* All are metals
* Occur only in compounds
* React with oxygen in the general formula EO (where O is oxygen and E is Group 2A element)

Group 3A

* Metalloids
* Includes Aluminum (the most abundant metal in the earth)
* Forms oxygen compounds with a X2O3 formula

Group 4A

* Includes metals and nonmetals
* Go from nonmetals at the top of the column to metals at the bottom
* All oxygen form compounds with a XO2 formula

Group 5A

* All elements form an oxygen or sulfur compound with E2O3 or E2S3 formulas

Group 6A

* Includes oxygen, one of the most abundant elements.
* Generally, oxygen compound formulas within this group are EO2 and EO3

Group 7A

* Elements combine violently with alkali metals to form salts
* Called halogens, which mean "salt forming"
* Are all highly reactive

Group 8A

* Least reactive group
* All elements are gases
* Not very abundant on earth
* Given the name noble gas because they are not very reactive

Charges in the Atom
The charges in the atom are crucial in understanding how the atom works. An electron has a negative charge, a proton has a positive charge and a neutron has no charge. Electrons and protons have the same magnitude of charge. Like charges repel, so protons repel one another as do electrons. Opposite charges attract which causes the electrons to be attracted to the protons. As the electrons and protons grow farther apart, the forces they exert on each other decrease.

Atomic Models and the Quantum Numbers
There are different models of the structure of the atom. One of the first models was created by Niels Bohr, a Danish physicist. He proposed a model in which electrons circle the nucleus in "orbits" around the nucleus, much in the same way as planets orbit the sun. Each orbit represents an energy level which can be determined using equations generated by Planck and others discussed in more detail below. The Bohr model was later proven to be incorrect, but provides a useful model for building an explanation.

The "accepted" model is the quantum model. In the quantum model, we state that the electron cannot be found precisely, but we can predict the probability, or likelihood, of an electron being at some location in the atom. You should be familiar with quantum numbers, a series of three numbers used to describe the location of some object (like an electron) in three-dimensional space:

1. n: the principal quantum number, an integer value (1, 2, 3...) that is used to describe the quantum level, or shell, in which an electron resides. The principal quantum number is the primary number used to determine the amount of energy in an atom. Using one of the first important equations in atomic structure (developed by Niels Bohr), we can calculate the amount of energy in an atom with an electron at some value of n:

En = -
Rhc

n2
where:
R = Rydberg constant, a value of 1.097 X 107 m-1
c = speed of light, 3.00 X 108 m/s
h = Planck's constant, 6.63 X 10 -34 J-s
n = principal quantum number, no unit

For example, how much energy does one electron with a principal quantum number of n= 2 have?

En = -
Rhc

n2
or
En = -
(1.097x107 m-1 ∗ (6.63x10-34 J•s)∗(3.0x108 m•s-1)

22
= 5.5x10-19 J

You might ask, well, who cares? In addition to the importance of knowing how much energy is in an atom (a very important characteristic!), we can also derive, or calculate, other information from this energy value. For example, can we see this energy? The table below suggests that we can. For example, suppose that an electron starts at the n=3 level (we'll call this the excited state) and it falls down to n=1 (the ground state). We can calculate the change in energy using the equation:

ΔE = hv = RH
1

ni2
-
1

nf2


Where:
ΔE = change in energy (Joules)
h = Planck's constant with a value of 6.63 x 10-34 (J-s)
ν is frequency (s-1)
RH is the Rydberg constant with a value of 2.18 x 10-18J.
ni is the initial quantum number
nf is the final quantum number

Using the equation below, we can calculate the wavelength and the frequency of the energy. The wavelength and the frequency give us information about how we might "see" the energy:

vλ = c
Where:
ν = the frequency of radiation (s-1)
λ = the wavelength (m)
c = the speed of light with a value of 3.00 x 108 m/s in a vacuum

Speed of light = 3.00E+08
Rydberg constant = 2.18E-18
Planck's constant = 6.63E-34

Excited state, n = 3 4 5
Ground state, n = 2 2 2
Excited state energy (J) 2.42222E-19 1.363E-19 8.72E-20
Ground state energy (J) 5.45E-19 5.45E-19 5.45E-19
ΔE = -3.02778E-19 -4.09E-19 -4.58E-19
ν = 4.56678E+14 6.165E+14 6.905E+14
λ(nm) = 656.92 486.61 434.47

2. l ("el", not the number 1): the azimuthal quantum number, a number that specifies a sublevel, or subshell, in an orbital. The value of the azimuthal quantum number is always one less than the principal quantum number n. For example, if n=1, then "el"=0. If n=3, then l can have three values: 0,1, and 2. The values of l are typically not identified as "0, 1, 2, and 3" but are more commonly called by their historic names, "s, p, d, and f", respectively. Since the quantum numbers were discovered through the study of light and lines on an electromagnetic spectra, chemists identified the lines by their quality: sharp, principal, diffuse and fundamental. The table below shows the relationship:

Value of l Subshell designation
0 s
1 p
2 d
3 f

3. m: the magnetic quantum number. Each subshell is composed of one or more orbitals. In the study of light, it was discovered that additional lines appeared in the spectra produced when light was emitted in a magnetic field. The magnetic quantum number has values between -l and +l. When l =1, for example, m can have three values: -1, 0, and +1. Because you know from the chart above that the subshell designation for l =1 is "p", you now know that the p orbital has three components. In your study of chemistry, you will be presented with px, py, and pz. Notice how the subscripts are related to a three-dimensional coordinate system, x, y, and z. The chart below shows a summary of the quantum numbers:

Principal Quantum Number (n) Azimuthal Quantum Number (l) Subshell Designation Magnetic Quantum Number (m) Number of orbitals in subshell
1 0 1s 0 1
2 0
1 2s
2p 0
-1 0 +1 1
3
3 0
1
2 3s
3p
3d 0
-1 0 +1
-2 -1 0 +1 +2 1
3
5
4 0
1
2
3 4s
4p
4d
4f 0
-1 0 +1
-2 -1 0 +1 +2
-3 -2 -1 0 +1 +2 +3 1
3
5
7

Chemists care about where electrons are in an atom or a molecule. In the early models, we believed that electrons move like billiard balls, and followed the rules of classical physics. The graphic below attempts to show that earlier models thought that we could identify the exact path, position, velocity, etc. of an electron or electrons in an atom:

A more accurate picture is that the electron(s) reside in a "cloud" that surrounds the nucleus of the atom. This concept is shown in the graphic below:

Chemists are interested in predicting the probability that the electron will be at some particular part of this cloud. The cloud is better known as an orbital, and comes in several different types, or shapes. Atomic orbitals are known as s, p, d, and f orbitals. Each type of atomic orbital has certain characteristics, such as shape. For example, as the graphic below shows, an s orbital is spherical in shape:

On this graph, the horizontal (x) axis represents the distance from the nucleus in units of a0, or atomic units. The value of a0 is 0.0529 nanometers (nm). The vertical (y) axis represents the probability density. What you should notice is that as the electron moves farther away from the nucleus, the probability of its being found at that distance decreases. In other words, the electron prefers to hang around close to the nucleus.

The three graphics below show some other orbitals. The first graph (top left) is of a "2s" orbital. Each "s" orbital can hold two electrons in its cloud. Notice how there is a relatively high probability of an electron being near the nucleus, then some space where the probability is close to zero, then the probability increases substantially at some distance from the nucleus. The graphic at the top right shows a "2p" atomic orbital. Orbitals that are "p" orbitals can hold up to six (6) electrons in their cloud. Notice its "dumbbell" or "figure of eight" shape. At the bottom left is a "3s" orbital. Again, notice its spherical shape. Finally, at the bottom right, is a "3p" orbital.


Determining Electron Configuration
One of the skills you will need to learn to succeed in freshman chemistry is being able to determine the electron configuration of an atom. An electron configuration is basically an account of how many electrons there are, and in what orbitals they reside under "normal" conditions. For example, the element hydrogen (H) has one electron. We know this because its atomic number is one (1), and the atomic number tells you the number of electrons. Where does this electron go? The one electron of hydrogen goes into the lowest energy state it possibly can, which means it will start at "level" one and goes into "s" orbitals first. We say that hydrogen has a "[1s1]" electron configuration. Looking at the next element on the Periodic Table --helium, or He -- we see it has an atomic number of two, so two electrons. Since " s" orbitals can hold up to two electrons, helium has an electron configuration of "[1s2]".

What about larger atoms? Let's look at carbon, with an atomic number of 6. Where do its 6 electrons go?

* First two: 1s2
* Next two: 2s2
* Last two: 2p2

We can therefore say that carbon has the electron configuration of "[1s22s22p2]".

The table below shows the subshells, the number of orbitals, and the maximum number of electrons allowed:

Subshell Number of Orbitals Maximum Number
of Electrons
s 1 2
p 3 6
d 5 10
f 7 14

The Abridged (shortened) Periodic Table below shows the electron configurations of the elements. Notice for space reasons we sometimes leave off a portion of the electron configuration. For example, look at argon (Ar), element 18. The table below shows its electron configuration as "[3s23p6]" (remembering that "p" orbitals can hold up to six (6) electrons). Its actual electron configuration is:

Ar = [1s22s22p63s23p6]

Sometimes you will see the notation: "[Ne]3s23p6", which means to include everything that is in neon (Ne, 10) plus the stuff in the "3"-level orbitals.

Try It Out

1. What is the frequency of infrared radiation that has a wavelength of 1.25 x 103 nm?